TRANSPOSITION OF LACTONE IN SESQUITERPENE LACTONE: CHEMICAL TRANSFORMATION OF α-SANTONIN INTO SESQUITERPENE α-METHYLENE-γ-LACTONE, YOMOGIN
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چکیده
منابع مشابه
Phytochemical Review Profile of Sesquiterpene Lactone Parthenin
Parthenin (a sesquiterpene lactone) is a major constituent of parthenium hysterophorus –a noxious weed known for its environmental and health hazardous properties. . It is responsible for imparting the several properties to this weed such as allelpathy, autotoxicity and allergencity. Further, anticancerous, antiameobic and antimalarial properties of the weed are also credited to parthenin. The ...
متن کاملSesquiterpene lactone variability in Parthenium hysterophorus L.
A population of Parthenium hysterophorus collected in Salta Argentina afforded two ambrosanolides, 2beta-hydroxycoronopilin and 1alpha,2beta,4beta-trihydroxypseudoguaian-6beta,12-olide, as well as five known others. Plants of the fructification from those transplanted from the Puna Argentina at 1200 m over the sea level produced hymenin.
متن کاملAromaticine, a sesquiterpene lactone from Amblyopappus pusillus
AROMATICINE (SYSTEMATIC NAME: 4a,8-dimethyl-3-methyl-ene-3,3a,4,4a,7a,8,9,9a-octa-hydro-azuleno[6,5-b]furan-2,5-dione), C(15)H(18)O(3), is a natural lactone isolated from Amblyopappus pusillus. The mol-ecular structure and conformation agree with the results of Romo, Joseph-Nathan & Díaz [(1964 ▶). Tetra-hedron, 20, 79-85]. The fused-ring system contains a seven-membered ring in a twist-boat co...
متن کاملCynaratriol, a sesquiterpene lactone from Centaurea musimomum
THE TITLE COMPOUND [SYSTEMATIC NAME: 3,8-dihydr-oxy-3-(hydroxy-meth-yl)-9-methyl-6-methyl-enedeca-hydro-azuleno[4,5-b]furan-2(3H)-one], C(15)H(22)O(5), is a sesquiterpene lactone showing the typical tricyclic guaianolide skeleton which has been isolated, together with other related metabolites, from the plant Centaurea musimomum. The present study confirms the mol-ecular structure, assigned by ...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1976
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1976.177